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超分子光化学

吴骊珠 佟振合

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Zheng Yi-wen et. al. published a paper on J. Am. Chem. Soc. on July 28, 2016.

We present a blueprint for aromatic C–H functionalization via a combination of photocatalysis and cobalt catalysis and describe the utility of this strategy for benzene amination and hydroxylation. Without any sacrificial oxidant, we could use the dual catalyst system to produce aniline directly from benzene and ammonia, and phenol from benzene and water, both with evolution of hydrogen gas under unusually mild conditions in excellent yields and selectivities.

技术支持 中国科学院武汉文献情报中心信息系统部(zsfw.whlib.ac.cn)